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Journal Article

Soot and Ash Deposition Characteristics at the Catalyst-Substrate Interface and Intra-Layer Interactions in Aged Diesel Particulate Filters Illustrated using Focused Ion Beam (FIB) Milling

2012-04-16
2012-01-0836
The accumulation of soot and lubrication-derived ash particles in a diesel particulate filter (DPF) increases exhaust flow restriction and negatively impacts engine efficiency. Previous studies have described the macroscopic phenomenon and general effects of soot and ash accumulation on filter pressure drop. In order to enhance the fundamental understanding, this study utilized a novel apparatus that of a dual beam scanning electron microscope (SEM) and focused ion beam (FIB), to investigate microscopic details of soot and ash accumulation in the DPF. Specifically, FIB provides a minimally invasive technique to analyze the interactions between the soot, ash, catalyst/washcoat, and DPF substrate with a high degree of measurement resolution. The FIB utilizes a gallium liquid metal ion source which produces Ga+ ions of sufficient momentum to directionally mill away material from the soot, ash, and substrate layers on a nm-μm scale.
Journal Article

Sensitivity Analysis of Ash Packing and Distribution in Diesel Particulate Filters to Transient Changes in Exhaust Conditions

2012-04-16
2012-01-1093
Current CJ-4 lubricant specifications place chemical limits on diesel engine oil formulations to minimize the accumulation of lubricant-derived ash in diesel particulate filters (DPF). While lubricant additive chemistry plays a strong role in determining the amount and type of ash accumulated in the DPF, a number of additional factors play important roles as well. Relative to soot particles, whose residence time in the DPF is short-lived, ash particles remain in the filter for a significant fraction of the filter's useful life. While it is well-known that the properties (packing density, porosity, permeability) of soot deposits are primarily controlled by the local exhaust conditions at the time of particle deposition in the DPF, the cumulative operating history of the filter plays a much stronger role in controlling the properties and distribution of the accumulated ash.
Journal Article

Ash Permeability Determination in the Diesel Particulate Filter from Ultra-High Resolution 3D X-Ray Imaging and Image-Based Direct Numerical Simulations

2017-03-28
2017-01-0927
Diesel engine exhaust aftertreatment components, especially the diesel particulate filter (DPF), are subject to various modes of degradation over their lifetimes. One particular adverse effect on the DPF is the significant rise in pressure drop due to the accumulation of engine lubricant-derived ash which coats the inlet channel walls effectively decreasing the permeability of the filter. The decreased permeability due to ash in the DPF can result in increased filter pressure drop and decreased fuel economy. A unique two-step approach, consisting of experimental measurements and direct numerical simulations using ultra-high resolution 3D imaging data, has been utilized in this study to better understand the effects of ash accumulation on engine aftertreatment component functionality.
Journal Article

In-Situ Optical Analysis of Ash Formation and Transport in Diesel Particulate Filters During Active and Passive DPF Regeneration Processes

2013-04-08
2013-01-0519
The formation and transport processes governing the build-up of incombustible ash deposits in diesel particulate filters (DPF) are influenced to a large extent by the filter's operating history. More specifically, the regeneration process, whether active, passive, or some variation of the two, has long been assumed to exert significant influence on the resulting ash characteristics. Until recently, only limited circumstantial evidence was available to describe differences in ash properties and distribution impacting DPF performance for filters subjected to different regeneration strategies. This work presents, for the first time, results from a comprehensive series of evaluations with optically-accessible DPF core samples showing the processes controlling the formation, transport, and interaction of the soot and ash deposits over a range of DPF regeneration conditions.
Journal Article

Ash Accumulation and Impact on Sintered Metal Fiber Diesel Particulate Filters

2015-04-14
2015-01-1012
While metal fiber filters have successfully shown a high degree of particle retention functionality for various sizes of diesel engines with a low pressure drop and a relatively high filtration efficiency, little is known about the effects of lubricant-derived ash on the fiber filter systems. Sintered metal fiber filters (SMF-DPF), when used downstream from a diesel engine, effectively trap and oxidize diesel particulate matter via an electrically heated regeneration process where a specific voltage and current are applied to the sintered alloy fibers. In this manner the filter media essentially acts as a resistive heater to generate temperatures high enough to oxidize the carbonaceous particulate matter, which is typically in excess of 600°C.
Journal Article

Theoretical and Experimental Analysis of Ash Accumulation and Mobility in Ceramic Exhaust Particulate Filters and Potential for Improved Ash Management

2014-04-01
2014-01-1517
Ash accumulation in the channels of ceramic, honeycomb-type particulate filters is controlled by several key parameters, which are the focus of this study. Ultimately, it is the formation of ash deposits, their transport, and the manner in which the ash accumulates in the particulate filter, which determines the useful service life of the filter and its resulting impact on engine performance. Although significant variations in ash deposit properties and their spatial distribution within the filter channels have been reported, depending on the filter's application, understanding the key parameters and mechanisms, such as the effects of exhaust flow and temperature conditions, as well as the processes occurring during filter regeneration events (whether passive or active) are critical in developing improved filter ash management strategies.
Journal Article

Direct Measurements of Soot/Ash Affinity in the Diesel Particulate Filter by Atomic Force Microscopy and Implications for Ash Accumulation and DPF Degradation

2014-04-01
2014-01-1486
Inorganic engine lubricant additives, which have various specific, necessary functions such as anti-wear, leave the combustion chamber bound to soot particles (approximately ≤1% by mass) as ash [13], and accumulate in aftertreatment components. The diesel particulate filter (DPF) is especially susceptible to ash-related issues due to its wall-flow architecture which physically traps most of the soot and ash emissions. Accumulated lubricant-derived ash results in numerous problems including increased filter pressure drop and decreased catalytic functionality. While much progress has been made to understand the macroscopic details and effects of ash accumulation on DPF performance, this study explores the nano- and micron-scale forces which impact particle adhesion and mobility within the particulate filter.
Journal Article

On the Nature of Particulate Emissions from DISI Engines at Cold-Fast-Idle

2014-04-01
2014-01-1368
Particulate emissions from a production gasoline direct injection spark ignition engine were studied under a typical cold-fast-idle condition (1200 rpm, 2 bar NIMEP). The particle number (PN) density in the 22 to 365 nm range was measured as a function of the injection timing with single pulse injection and with split injection. Very low PN emissions were observed when injection took place in the mid intake stroke because of the fast fuel evaporation and mixing processes which were facilitated by the high turbulent kinetic energy created by the intake charge motion. Under these conditions, substantial liquid fuel film formation on the combustion chamber surfaces was avoided. PN emissions increased when injection took place in the compression stroke, and increased substantially when the fuel spray hit the piston.
Journal Article

Effect of Operation Strategy on First Cycle CO, HC, and PM/PN Emissions in a GDI Engine

2015-04-14
2015-01-0887
The impact of the operating strategy on emissions from the first combustion cycle during cranking was studied quantitatively in a production gasoline direct injection engine. A single injection early in the compression cycle after IVC gives the best tradeoff between HC, particulate mass (PM) and number (PN) emissions and net indicated effective pressure (NIMEP). Retarding the spark timing, it does not materially affect the HC emissions, but lowers the PM/PN emissions substantially. Increasing the injection pressure (at constant fuel mass) increases the NIMEP but also the PM/PN emissions.
Journal Article

Design Drivers of Energy-Efficient Transport Aircraft

2011-10-18
2011-01-2495
The fuel energy consumption of subsonic air transportation is examined. The focus is on identification and quantification of fundamental engineering design tradeoffs which drive the design of subsonic tube and wing transport aircraft. The sensitivities of energy efficiency to recent and forecast technology developments are also examined.
Journal Article

Energy Efficient HVAC System with Spot Cooling in an Automobile - Design and CFD Analysis

2012-04-16
2012-01-0641
Spot, or distributed, cooling and heating is an energy efficient way of delivering comfort to an occupant in the car. This paper describes an approach to distributed cooling in the vehicle. A two passenger CFD model of an SUV cabin was developed to obtain the solar and convective thermal loads on the vehicle, characterize the interior thermal environment and accurately evaluate the fluid-thermal environment around the occupants. The present paper focuses on the design and CFD analysis of the energy efficient HVAC system with spot cooling. The CFD model was validated with wind tunnel data for its overall accuracy. A baseline system with conventional HVAC air was first analyzed at mid and high ambient conditions. The airflow and cooling delivered to the driver and the passenger was calculated. Subsequently, spot cooling was analyzed in conjunction with a much lower conventional HVAC airflow.
Journal Article

Oil Transport from Scraper Ring Step to Liner at Low Engine Speeds and Effect of Dimensions of Scraper Ring Step

2016-04-05
2016-01-0495
In gasoline engines, a scraper ring with a step on the bottom outer edge is widely used as a second ring. However, there lacks a fundamental understanding on the effects of this feature and its dimensions on oil transport. Inspired by observations from visualization experiments, this work combining computational fluid dynamics (CFD) and theoretical analysis shows that oil can be trapped in the space bordered by a second ring step and the chamfer of a piston third land. The trapped oil can be released to a liner when the piston is approaching the top dead center (TDC). This additional oil on the liner becomes a potential source of oil consumption. Such oil transport has been observed at typically less than 1500rpm. Since road vehicles often operate in this speed range, the newly-observed oil trapping and release can be closely associated with oil consumption in gasoline engines. In this work, a comprehensive study on oil trapping and release will be demonstrated.
Technical Paper

Differences between On Board Diagnostic Systems (EOBD, OBD-II, OBD-BR1 and OBD-BR2)

2006-11-21
2006-01-2671
The Gasoline Engine Management Systems for passenger cars have the OBD-II (On Board Diagnostic) for United States of America market, the EOBD (European On Board Diagnostic) for Europe and OBD-BR1 and OBD-BR2 for Brazil. This paper presents the differences between these four On Board Diagnostic Systems.
Technical Paper

Engine-Out “Dry” Particular Matter Emissions from SI Engines

1997-10-01
972890
The Engine-Out Particulate Matter (EOPM) was collected from a spark ignition engine operating in steady state using a heated quartz fiber filter. The samples were weighted to obtain an EOPMindex and were analyzed using Scanning Electron Microscopy. The EOP Mindex was not sensitive to the engine rpm and load. When the mixture is very rich (air equivalence ratio λ less than ∼ 0.7), the EOPM comprise mostly of soot particles from fuel combustion. In the lean to slightly rich region (0.8 < λ < 1.2), however, the EOPM are dominated by particles derived from the lubrication oil.
Technical Paper

Combustion Chamber Deposit Effects on Hydrocarbon Emissions from a Spark-Ignition Engine

1997-10-01
972887
A dynamometer-mounted four-cylinder Saturn engine was used to accumulate combustion chamber deposits (CCD), using an additized fuel. During each deposit accumulation test, the HC emissions were continuously measured. The deposit thickness at the center of the piston was measured at the beginning of each day. After the 50 and 35-hour tests, HC emissions were measured with isooctane, benzene, toluene, and xylene, with the deposited engine, and again after the deposits had been cleaned from the engine. The HC emissions showed a rapid rise in the first 10 to 15 hours and stabilization after about 25 hours of deposit accumulation. The HC increase due to CCD accumulation accounted for 10 to 20% of the total engine-out HC emissions from the deposit build-up fuel and 10 to 30% from benzene, isooctane, toluene, and xylene, making CCDs a significant HC emissions source from this engine. The HC emissions stabilized long before the deposit thickness.
Technical Paper

Contribution of Oil Layer Mechanism to the Hydrocarbon Emissions from Spark-Ignition Engines

1997-10-01
972892
A research program designed to measure the contribution from fuel absorption in the thin layer of oil, lubricating the cylinder liner, to the total and speciated HC emissions from a spark ignition engine has been performed. The logic of the experiment design was to test the oil layer mechanism via variations in the oil layer thickness (through the lubricant formulations), solubility of the fuel components in the lubricants, and variations in the crankcase gas phase HC concentration (through crankcase purging). A set of preliminary experiments were carried out to determine the solubility and diffusivity of the fuel components in the individual lubricants. Engine tests showed similar HC emissions among the tested lubricants. No consistent increase was observed with oil viscosity (oil film thickness), contrary to what would be expected if fuel-oil absorption was contributing significantly to engine-out HC. Similarly, no effect of crankcase purging could be observed.
Technical Paper

Thermally-Induced Microstructural Changes in a Three-Way Automotive Catalyst

1997-10-01
972905
The use of advanced electron microscopy techniques to characterize both the bulk and near-atomic level microstructural evolution of catalyst materials during different dynamometer/vehicle aging cycles is an integral part of understanding catalyst deactivation. The study described here was undertaken to evaluate thermally-induced microstructural changes which caused the progressive loss of catalyst performance in a three-way automotive catalyst. Several different catalyst processing variables, for example changing the washcoat ceria content, were also evaluated as a function of aging cycle and thermal history. A number of thermally-induced microstructural changes were identified using high resolution electron microscopy techniques that contributed to the deactivation of the catalyst, including sintering of all washcoat constituents, γ-alumina transforming to α-, β-, and δ-alumina, precious metal redistribution, and constituent encapsulation.
Technical Paper

The Effect of Operating Conditions at Idle in the S.I. Engine

1997-10-01
972990
A gasoline engine with an electronically controlled fuel injection system has substantially better fuel economy and lower emissions than a carburetted engine. In general, the stability of engine operation is improved with fuel injector, but the stability of engine operation at idle is not improved compared with a carburetted gasoline engine. In addition, the increase in time that an engine is at idle due to traffic congestion has an effect on the engine stability and vehicle reliability. Therefore, in this research, we will study the influence of fuel injection timing, spark timing, dwell angle, and air-fuel ratio on engine stability at idle.
Technical Paper

Lean NOx Trap for Heavy-Duty On-Road Applications - A Feasible Alternative?

2007-10-30
2007-01-4179
The implementation and development efforts of lean NOx trap catalysts for heavy-duty applications decreased a number of years ago. Most heavy-duty engine manufacturers realized that the system complexity as well as the durability of such a system does not allow large volume production without significant risk. The current consensus of the heavy-duty community is that for 2010 the SCR system will be the prime path to meet the 0.2 g/bHPhr NOx emission standard, although this is subject to adequate infrastructure investment and progress. As a low volume manufacturer, in order to comply with the 2007 heavy-duty phase-in emission standards, General Engine Products (a subsidiary of AM General LLC) integrated a NOx adsorber system on the Optimizer 6500 engine. This engine features split combustion chamber design, rotary fuel injection pump and operates with EGR.
Technical Paper

Assessing the Windage Tray Blockage Effect on Aeration in the Oil Sump

2007-10-29
2007-01-4109
The windage tray effect on aeration in the engine sump was assessed by replacing much of the windage tray materials with wire meshes of various blockages. The mesh was to prevent direct impact of the oil drops spinning off the crank shaft onto the sump oil, and simultaneously, to provide sufficient drainage so that there was no significant build up of windage tray oil film that would interact with these droplets. Aeration at the oil pump inlet was measured by X-ray absorption in a production V-6 SI engine motoring at 2000 to 6000 rpm. Within experimental uncertainty, these windage tray changes had no effect on aeration. Thus activities in the sump such as the interaction of the oil drops spun from the crank shaft with the sump oil or with the windage tray, and the agitation of the sump oil by the crank case gas, were not major contributors to aeration at the pump inlet.
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